Our Group organises 3000+ Global Events every year across USA, Europe & Asia with support from 1000 more scientific Societies and Publishes 700+ Journals which contains over 50000 eminent personalities, reputed scientists as editorial board members.
Semi-crystalline polymers offer many advantageous properties which are required for phase change materials (PCM) in
latent heat storages. They exhibit high heats of fusion and a wide range of melting temperatures. Additionally, specific
characteristics (e.g. thermal conductivity) can be easily tailored via compounding. However, only high-density polyethylene
(HDPE) has been considered as suitable PCM so far. A Differential Scanning Calorimeter (DSC) was first used to identify
candidate polymer classes according to their storage capacity and application temperature. The most promising polymer
types were found to be: polyethylene (PE), polypropylene (PP), polyamides (PA), polyoxymethylene (POM) and polyethylene
glycol (PEG). An HDPE, a PA 6, a PA 4.6 and a POM copolymer were further selected for application-oriented stability
investigations. Cyclic and static thermal loads were applied to examine their thermal and thermo-oxidative stability. Thermal
cycling was done in a DSC up to 3000 cycles in air and nitrogen atmosphere and thermo-physical characteristics were recorded
simultaneously. Whereas the PA 4.6 degraded steadily, the thermo-physical characteristics of HDPE and the PA 6 were not
affected. The stability of POM could be improved by utilizing a closed system. Static thermal outsourcing was done above
melting temperature in circulating air ovens. Fourier Transform Infrared Spectroscopy (FTIR) revealed that degradation
occurred mainly on the surface leaving the storage-relevant characteristics of the bulk unaffected. These results outline the
applicability of polymers as PCM. This research project is funded by Klima- und Energiefonds (Austrian Climate and Energy
Funds) and carried out within the framework of the program “Energieforschung”. The Austrian Research Promotion Agency
(FFG) is gratefully acknowledged for funding this work under Grant No. 848914 (StoreITup-IF).
Biography
Helena Weingrill is a PhD student at the Chair of Materials Science and Testing of Polymers at Montanuniversitaet Leoben in Austria. She finished the bachelor’s and master’s programme of Polymer Science and Engineering also at the Montanuniveritaet Leoben.